Modern Gold Catalyzed Synthesis by A. Stephen K. Hashmi, F. Dean Toste

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By A. Stephen K. Hashmi, F. Dean Toste

With its outstanding positive factors, gold has resulted in thoroughly new response kinds in recent times, which in flip have strongly prompted both
natural catalysis and fabric technological know-how. different fields the place an important volume of recent effects has been got comprise nanotechnology,
self assembly/supramolecular structures and biochemical/medicinal chemistry. consequently, gold is among the most popular subject matters in catalysis at
the instant, with an expanding quantity of analysis being conducted during this field.
whereas targeting homogeneous catalysis, this monograph additionally covers the most purposes in heterogeneous catalysis. Following
a glance on the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it is going directly to talk about gold-catalyzed additions to allenes and
alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, in addition to oxidation and relief reactions.
the complete is done off with a piece on gold-catalyzed aldol and comparable reactions and the appliance of gold-catalyzed reactions to natural
product synthesis.
Of curiosity to man made chemists and inorganic chemists, in addition to natural chemists operating in homogeneous catalysis, actual and
technical chemists.Content:
Chapter 1 Hydrochlorination of Acetylene Catalyzed by means of Gold (pages 1–26): Marco Conte and Graham J. Hutchings
Chapter 2 Gold?Catalyzed relief Reactions (pages 27–54): Avelino Corma and Pedro Serna
Chapter three Gold?Catalyzed Benzannulations: Asao–Yamamoto Benzopyrylium Pathway (pages 55–73): Naoki Asao and Yoshinori Yamamoto
Chapter four Gold?Catalyzed Reactions of Propargyl Esters, Propargyl Alcohols, and similar Compounds (pages 75–134): Pablo Mauleon and Prof. F. Dean Toste
Chapter five Intramolecular Hydroarylation of Alkynes (pages 135–152): Paula de Mendoza and Antonio M. Echavarren
Chapter 6 Gold–Alkyne Complexes (pages 153–173): Maria Agostina Cinellu
Chapter 7 Gold–Alkene Complexes (pages 175–199): Maria Agostina Cinellu
Chapter eight Hydration and Hydroalkoxylation of CC a number of Bonds (pages 201–235): J. Henrique Teles
Chapter nine Gold?Catalyzed Aldol and similar Reactions (pages 237–261): Christoph Hubbert and Prof. Dr. A. Stephen ok. Hashmi
Chapter 10 Gold?Catalyzed Oxidation Reactions: Oxidation of Alkenes (pages 263–272): Yuanhong Liu
Chapter eleven Gold?Catalyzed Oxygen?Atom move to Alkynes (pages 273–296): Maria Camila Blanco Jaimes and Prof. Dr. A. Stephen okay. Hashmi
Chapter 12 Gold?Catalyzed Additions to Alkenes: N?Nucleophiles (pages 297–302): Zigang Li, David A. Capretto and Chuan He
Chapter thirteen Gold?Catalyzed Additions to Alkenes: O?Nucleophiles (pages 303–307): Zigang Li, David A. Capretto and Chuan He
Chapter 14 Oxidation of Alcohols and Carbohydrates (pages 309–329): Cristina Della Pina, Ermelinda Falletta and Michele Rossi
Chapter 15 functions of Gold?Catalyzed Reactions to usual Product Synthesis (pages 331–362): Matthias Rudolph
Chapter sixteen Gold?Catalyzed Addition Reactions to Allenes (pages 363–389): Christian iciness and Norbert Krause

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19). The need for a distorted axial symmetry of the alkynes with respect to the plane containing the chloride is further sustained by the circumstance that as the alkyne becomes more sterically hindered, the reaction becomes more inhibited [38]. 19 The formation of a Au–acetylene–HCl complex (24) is assumed to explain the acetylene hydrochlorination with the formation of a six-membered ring. 7 Proposed model for the hydrochlorination of acetylene over Au/C, assuming the active species to be AuCl4À centers on the catalyst surface [38].

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