Developments in Dielectric Materials and Electronic Devices, by K. M. Nair, Ruyan Guo, Amar S. Bhalla, S.-I. Hirano, D.

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By K. M. Nair, Ruyan Guo, Amar S. Bhalla, S.-I. Hirano, D. Suvorov

Papers during this quantity comprise subject matters comparable to fabrics synthesis and processing; relaxors; novel compositions; fabric layout; fabrics for multilayer digital units; processing-microstructure-property courting; purposes; environmental matters; and economic/cost research of tomorrow's digital units. comprises 38 papers.Content:

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I. Shirasaki and H. Yamamura, "Effects of Excess PbO on the Densification of PLZT Ceramics," Journal of the American Ceramic Society, 72 15)833-836(1989). (15) C. Liu, B. Zou, , A. J. Rondinone and Z. J. Zhang, "Sol-Gel Synthesis of Freestanding Ferroelectric Lead Zirconate Titanate Nanoparticles," Journal of the American Chemical Society, 123 4344 - 4345 (2001). (16) M. Marinsek, K. Zupan and J. Maeek, "Ni-YSZ Cermet Anodes Prepared by Citrate / Nitrate Combustion Synthesis," Journal of Power Sources, 106 178 - 188 (2002).

3b) contain slightly larger ( 2 - 6 μπι) grains but are also single-phase and dense. Developments in Dielectric Materials and Electronic Devices · 23 Sintering Temperature (°C) Fig. 2 Weight loss on sintering pellets of LZT and NZT Structure of LZT The x-ray pattern for LZT powder shown in Fig. 8898 A. 6105 A). The reflection labelled as a in Fig. 4 can only be indexed as Vi{3\ 1}, corresponding to antiphase tilting of oxygen octahedra5. Those marked as βι, Ρ2, ... are reflections of the type Vi{even, even, odd), corresponding to antiparallel displacement of La+3 ions.

Another possibility consists in refining the particle size of the intial powders. Ultrafme alkaline niobate powders have been obtained by various chemical synthesis routes. 13 used an mechanochemical approach and demonstrated, how LiNbC>3 powders could be obtained just by low temperature intensive milling of LÍ2CO3 with Nb25 in a planetary mill without any additional calcination treatment. The disadvantages of this method, however, are long processing times and small batch sizes. Another approach is the hydrothermal synthesis of alkaline niobates, by which ND2O5 is processed in a aqueous solution of alkali metal hydroxides in an autoclave14,5.

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