Catalyzed Carbon-Heteroatom Bond Formation by Andrei K. Yudin, John F. Hartwig

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By Andrei K. Yudin, John F. Hartwig

Written by way of an skilled editor commonly acclaimed in the medical group, this booklet covers every thing from oxygen to nitrogen functionalities. From the contents:

  • Palladium-Catalyzed Syntheses of 5-membered Saturated Heterocycles
  • The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by means of Substitution and Addition Reactions Catalyzed through Transition steel Complexes
  • Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes
  • Palladium-Catalyzed Formation of fragrant Heterocycles
  • Rhodium-Catalyzed Amination of C-H-Bonds
  • Transition Metal-Catalyzed Synthesis of Heterocycles
  • Copper-Catalyzed Synthesis of Azoles
  • Palladium(II)-Catalyzed C-N Bond Formation regarding Aminopalladation of Aklenes
  • Carbon-Heteroatom Bond Formation via Rh(I)-Catalyzed Ring-Opening Reactions
  • fresh Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds

The result's an necessary resource of knowledge for the strategic making plans of the bogus routes for natural, catalytic and medicinal chemists, in addition to chemists in undefined.

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In contrast, modern transition metal catalysis has provided many complementary synthetic approaches to lactones that have enabled a greater number of retrosynthetic connections. , minimization of waste). In addition, extension to asymmetric variants allows direct synthesis of chiral lactones from achiral starting materials. Herein, we discuss lactonization strategies that involve the formation of CÀO bonds made possible by employment of transition metals. 1 Natural products containing lactone functionalities [1, 4].

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