Carbohydrate Chemistry Volume 10 by J S Brimacombe

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Perkin I, 1976, 1395. ls2 Other 1,6-anhydro-sugars are referred to in Chapters 6 , 7, 11, and 23. 181 lSa R. Chaby and P. , 1976, 49,489. K. Takeo, K. Mine, and T . , 1976,48, 197. lS3 4,6-Dichloro-4,6-dideoxy-~-gaIactose reacted with cyclohexanone ethylene acetal in the presence of an acid catalyst to give the acyclic derivative (48), which was converted into the corresponding 5 - u l 0 s e . ~ Treatment ~~ with base converted (48) into the 5,6-anhydro-derivative, which was hydrolysed to give the L-idose diacetal(49), presumably by way of a 4,5-anhydro-~-glucosederivative.

Lsa M. Poje, B. Mihanovic, and P. Mildner, Bull. , Cons. Acad. Sci. F. , Sect. A , 1975,20,273 (Chem. , 1976, 84, 59 928w). 127a 128 Carbo hydra t e Chemistry 22 The S-aryl bond of 2,4-dinitrophenyl 1 -thio-/%D-glucopyranoside was cleaved on treatment with benzyl bromide, the benzyl carbonium ion presumably acting as a sulphur-specific Lewis C-G1ycosides Details of the synthesis and reactions of glycofuranosylethynes, prepared via the reaction of 2,3:5,6-di-O-isopropylidene-a-~-mannofuranose with ethynyl magnesium bromide, have been published (see Vol.

Evstigneeva, Zhur. org. , 1976, 12, 960 (Chem. , 1976, 85, 94 647w). J, G. Buchanan, A. D. Dunn, and A. R. S. Perkin I, 1976, 68. S. D. Shiyan, 0. E. Lakhtina, M. L. Shul’man, and A. Ya. Khorlin, Izvest. Akad. , Ser. , 1976, 197 (Chem. , 1976, 84, 150 852c). A. Rosenthal and A. J. Brink, J. Carbohydrates, Nucleosides, Nucleotides, 1975, 2, 343. A. Rosenthal and M. Ratcliffe, Canad. J. , 1976, 54, 91. K. Hata, M. Kozawa, and K. Baba, Chem. and Pharm. Bull. (Japan), 1976, 24, 1688. H. Wagner and G.

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