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1. Chiral Ligands for A s y m m e t r i e Catalysis 35 Catalysts having supported DIOP units have been particularly well studied (128a, b). Supported BPPM also has been investigated (65). Supported BPPM also has been investigated (65) as well as a cyclic chiral 1,2-diphosphine (156). It is difficult to predict the future of asymmetric catalysis. Because it is one of the most economical ways to produce chiral compounds, it can be expected that a substantial effort will be made to develop sophisticated systems involving a continuing search for effective matches of ligands and prochiral substrates.
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And Otsuka, S. (1978). J. Am. Chem. Soc. 100,3443. , Green, Μ. , and Mislow, K. (1968). J. Am. Chem. Soc. 90,4835. , and Bosnich, B. (1977). J. Am. Chem. Soc. 99, 6253. Solladie, G. (1981). Synthesis p. 185. , and Drabowicz, J. (1982). Top. Stereochem. 13, 333. James, B. , and McMillan, R. S. (1977). Can. J. Chem. 55, 3927. James, B. , McMillan, R. , Morris, R. , and Wang, D . K. W. (1978). Adv. Chem. Ser. 167, 122. Calhoun, A. , Kobos, W. , Nile, Τ. , and Smith, C. A. (1979). J. Organomet. Chem.