Annual Reports in Organic Synthesis–1984 by Martin J. O'Donnell, Louis Weiss, Louis M. Weiss

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By Martin J. O'Donnell, Louis Weiss, Louis M. Weiss

Annual experiences in natural Synthesis—1984 is a bibliography of papers on natural synthesis from basic chemistry journals. issues lined variety from carbon-carbon bond forming reactions to oxidations, mark downs, synthesis of heterocycles, and artificial arrangements.
This e-book comprises seven chapters and starts off with a listing of papers on carbon-carbon bond forming reactions, together with carbon-carbon unmarried, double, and triple bonds. The chapters that stick to specialize in oxidations and discount rates, equipment of synthesizing heterocyclic platforms, and using maintaining teams. Synthetically worthy ameliorations that don't healthy simply into the 1st 3 chapters are thought of subsequent, with emphasis on sensible workforce synthesis, ring enlargement and contraction, and beneficial multistep variations. the ultimate bankruptcy bargains with miscellaneous studies on themes starting from cycloadditions to uneven catalysis, metalation, electrophilic substitutions, and pyrylium-mediated changes of basic amino teams into different practical teams.
This monograph should be of price to natural chemists, either expert and nonspecialist in synthesis.

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106. 5028 (1984). R\ -CI 1) X M g ^ ' ^ ^ ^ R ^ ^ R^ 68-98% 2) 0 0 Unsymmetrical a11y1-a11y1 coupling gives 1,5-dienes. 5-3 K. Sakai et a l . , Chem. Pharm. B u l l . , J2_, 4632 (1984); B. Mauze, P. Ongoka and L. M i g i n i a c , J . Organometal. , 264, 1 (1984); R. B. Bates et a l . , J . Org. , 49, 2981 11984). 1) s-BuLi TMEDA 2) E^ 25-81% Ε = RX, RCHO, R 2 C = 0 , RSSR, O 2 . 5-4 K. Koumaglo and T . H. Chan, Tetrahedron L e t t . , 717 (1984). 5-5 G. T r i m i t s i s e t a l . , Chem. Commun..

J p n . , 57, 1637 (1984); M. Kodama e t a l . , Tetrahedron L e t t . , 25, 5781 (1984). 0S02Me MeSO^O 1) 2 MeSCHSOMe THF, 0°C 2) Aq. NH^Cl THPO* OSiR, 3) NBS, CaCO, Aq. 4-14 D. L i o t t a , Acc. Chem. R e s . J[7, 28 (1984). 5. G). H. Sugimura and H. T a k e i , Chem. L e t t . 1505 (1984). 5-2 A. Goliaszewski and J . Schwartz, J . Am. Chem. S o c . 106. 5028 (1984). R\ -CI 1) X M g ^ ' ^ ^ ^ R ^ ^ R^ 68-98% 2) 0 0 Unsymmetrical a11y1-a11y1 coupling gives 1,5-dienes. 5-3 K. Sakai et a l . , Chem.

5-14 B. H. L i p s h u t z , R. S. Wilhelm and J . A. Kozlowski, Tetrahedron, 40, 5005 (1984). 5-15 B. H. Lipshutz et a l . , J . Org. , 49, 3928, 3938, 3943 (1984); G. W. Ebert and R. D. Rieke, i b i d , 49, 5280 (1984). Br R2Cu(CN)Li, THF 7->95% F u l l Papers: S u b s t i t u t i o n and Conjugate Additions o f Higher Order Mixed Cuprates. 5-16 T . Kikukawa, M. Imaida and A. T a i , B u l l . Chem. Soc. J p n . , 57, 1954 (1984); J . R. Pougny, Tetrahedron L e t t . , 25, 2363 (T984). 5-17 P.

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